I had a question off-list about how to do this, so I guess
some other people will benefit from an example of how to set
this up.
To:domain.com error:550 5.1.1 No such user
To:postmaster@domain.com OK
To:user1@domain.com OK
To:user2@domain.com OK
then (cd /etc/mail; sudo makemap hash access < access)